I've been on a Sam Rockwell kick recently. The opening song puts it right in the fun mood, and Sammy rocks it out of the park as he does throughout, Anne K is nice as well, very fun movie.
Good one. This and "Live and Let Die" are my two favorite Bond theme songs, and I've seen every Bond film at least a couple of times. And there are a few that I've seen a couple of DOZEN times.
OK, as a lover of classic movies, I've gotta post this:
I don't know if it's the "best" song ever associated with a movie, but no song was ever more closely associated with one. And people will still make that connection 200 yrs from now. The newer songs posted in this thread...maybe not.